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Activated Carbon As its Used For Water Filtration.

Last up dated on March 18, 2007

Carbon, in various forms, has been used to adsorb contaminants for some time. The first documented use of carbon as an adsorbent was for medical purposes, in the form of wood char in 1550 B.C. The first documented use for water treatment was in 200 B.C.to remove disagreeable tastes. The understanding of carbon adsorption progressed in the late 19th and early 20th centuries, when vapor phase organic carbon was developed and given its first widespread use as a defense against gas warfare during WWI. By the late 1960s and early 1970s, GAC was found to be very effective at removing a broad spectrum of synthetic chemicals from water and gases.

Carbon

Activated carbon (AC) filters contain either granular activated carbon (GAC) or powdered block carbon (PAC). The amount of AC in a filter is one of the most important characteristics affecting the amount and rate of contaminate removal. More carbon in a cartridge means more capacity for chemical removal, resulting in longer cartridge lifetime.

Because AC systems are limited in the types of compounds they can effectively remove,it is essential that the homeowner determine which water contaminants are present before purchasing any type of water purification system.

AC is most effective at removing organic compounds such as volatile organic compounds, pesticides and benzene. It can also remove some metals, chlorine and radon. As with any treatment system, it cannot remove all possible drinking water contaminants.

AC can be extremely effective for the removal of emerging contaminants. In the study described here, both PAC and GAC were capable of removing nearly all compounds evaluated by greater than 90%.

Rust, scale, sand or other sediments can clog any AC filter. A solution to this problem is to place sediment filter between the cartridge and incoming water. When sediment filters become clogged, they will cause a pressure drop and need to be replaced.
An AC filter must be deep enough so that the pollutants will adsorb to the AC in the time it takes the water to move through the filter. The appropriate filter depth depends on the flow rate of water through the filter. The slower the flow rate, the better the removal.

AC filters can be excellent places for bacteria to grow. Conditions for bacterial growth are best when the filter is saturated with organic contaminants, which supply the food source for the bacteria, and when the filter has not been used for a long period of time. It is still unclear whether the bacteria growing on the carbon poses a health threat. Some manufacturers have placed silver in the AC in order to prevent the growth of bacteria.

Some cartridges are sold with predictions about their longevity. These are generally only crude estimates since they do not take into consideration factors that are characteristic to a specific water source, such as pollutant concentration.

Water contaminants that can be reduced to acceptable standards by activated carbon filtration

(Water Quality Association, 1989)

Contaminant *MCL,  mg/L
Inorganic Contaminants
Organic Arsenic Complexes 0.05
Organic Chromium Complexes 0.05
Mercury (Hg+2) Inorganic 0.05
Organic Mercury Complexes 0.002
 
Organic Contaminants *MCL,  mg/L
Benzene 0.005
Endrin 0.0002
Lindane 0.004
Methoxychlor 0.1
1,2 dichloroethane 0.005
1,1-dichloroethylene 0.007
1,1,1, trichloroethane 0.200
1.,1,1, trichloroethane 0.10
Toxaphene 0.005
Trichloroethylene 0.005
2,,4-D 0.1
2,4, 5-TP (Silvex) 0.01
Para-dichlorobenzene 0.075
Secondary Drinking Water Standards
Contaminant **SMCL
Color 15 color units
Foaming Agents (MBAS) 0.5 mg/L
Odor 3 threshold odor number
 
*Maximum Contaminant Level
**Secondary Maximum Contaminant Level

 

AC Filter Guidelines

  1. Know the quantity of AC in the filter since this will determine the amount and rate of contamination removal.
  2. Use prefilter to add life to AC filters.
  3. Replace prefilters and AC filters regularly.
  4. Determine appropriate intervals of replacement based on contaminant concentration, flow rate, depth of filter, amount of AC and prefilter. Retailers can help in this analysis.

 

Literature Cited

U.S. Army Corps of Engineers Engineering and Design ADSORPTION DESIGN GUIDE DG 1110-1-2

COOPERATIVE EXTENSION SERVICE, MANHATTAN, KANSAS MF-883 Revised Effect of Point-of-Use, Activated Carbon Filters

Bacteriological Quality of Rural Groundwater Supplies APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Dec. 1995, p. 4291–4295

Effects of activated carbon and bacteriostatic filters on microbiological quality of drinking water. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Mar. 1981, p. 646-651